This paper uses references and PMC index model to establish an evaluation system based on 10 typical cases of water pollution control policies, which have been evaluated according to PMC index and PMC stereoscopic surface, aiming at offering references for high-quality green development and coordinated human\|water environment. Among the policies, 1 is perfect, 5 are excellent and the rest are acceptable. Their average PMC index is 8.17, suggesting a generally rational water pollution control policy design in China. This paper presents suggestions on optimizing water pollution control policies based on China's actual water ecological management from government-oriented mutual management, laws and supervision, increasing governmental and market capital input and intensifying technical supports, constructing balanced policy system, and encouraging diversified involvement and boosting ecological culture propaganda.